NIOSH Publication No. 2005-151:

NIOSH Pocket Guide to Chemical Hazards

September 2005

sec-Butyl alcohol

CAS
78-92-2

CH3CH(OH)CH2CH3

RTECS
EO1750000
Synonyms & Trade Names

2-Butanol, Butylene hydrate, 2-Hydroxybutane, Methyl ethyl carbinol
DOT ID & Guide
1120 / 129

Exposure
Limits

NIOSH REL: TWA 100 ppm (305 mg/m3) ST 150 ppm (455 mg/m3)
OSHA PEL: TWA 150 ppm (450 mg/m3)
IDLH
2000 ppm See: 78922
Conversion
1 ppm = 3.03 mg/m3
Physical Description
Colorless liquid with a strong, pleasant odor.
MW: 74.1
BP: 211°F
FRZ: -175°F
Sol: 16%
VP: 12 mmHg
IP: 10.10 eV

Sp.Gr: 0.81
Fl.P: 75°F
UEL(212°F): 9.8%
LEL(212°F): 1.7%

Class IC Flammable Liquid: Fl.P. at or above 73F and below 100F.
Incompatibilities & Reactivities

Strong oxidizers, organic peroxides, perchloric & permonosulfuric acids
Measurement Methods
NIOSH 1405, 1450; OSHA 7
See: NMAM or OSHA Methods
Personal Protection & Sanitation
(See protection)
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated
Remove: When wet (flammable)
Change: No recommendation

First Aid
(See procedures)
Eye: Irrigate immediately
Skin: Water flush promptly
Breathing: Respiratory support
Swallow: Medical attention immediately
Respirator Recommendations
NIOSH
Up to 1000 ppm:
(APF = 10) Any chemical cartridge respirator with organic vapor cartridge(s)*
(APF = 10) Any supplied-air respirator*
Up to 2000 ppm:
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode*
(APF = 25) Any powered, air-purifying respirator with organic vapor cartridge(s)*
(APF = 50) Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s)
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister
(APF = 50) Any self-contained breathing apparatus with a full facepiece
(APF = 50) Any supplied-air respirator with a full facepiece
Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister/Any appropriate escape-type, self-contained breathing apparatus
Important additional information about respirator selection
Exposure Routes
inhalation, ingestion, skin and/or eye contact
Symptoms
Irritation eyes, skin, nose, throat; narcosis
Target Organs
Eyes, skin, respiratory system, central nervous system
See also: INTRODUCTION   See ICSC CARD: 0112