NIOSH Publication No. 2005-151:

NIOSH Pocket Guide to Chemical Hazards

September 2005

Carbon monoxide

CAS
630-08-0

CO

RTECS
FG3500000
Synonyms & Trade Names

Carbon oxide, Flue gas, Monoxide
DOT ID & Guide
1016 / 119
9202 / 168 (cryogenic liquid)

Exposure
Limits

NIOSH REL: TWA 35 ppm (40 mg/m3) C 200 ppm (229 mg/m3)
OSHA PEL†: TWA 50 ppm (55 mg/m3)
IDLH
1200 ppm See: 630080
Conversion
1 ppm = 1.15 mg/m3
Physical Description
Colorless, odorless gas. [Note: Shipped as a nonliquefied or liquefied compressed gas.]
MW: 28.0
BP: -313°F
MLT: -337°F
Sol: 2%
VP: >35 atm
IP: 14.01 eV
RGasD: 0.97

Fl.P: NA (Gas)
UEL: 74%
LEL: 12.5%

Flammable Gas
Incompatibilities & Reactivities

Strong oxidizers, bromine trifluoride, chlorine trifluoride, lithium
Measurement Methods
NIOSH 6604; OSHA ID209, ID210
See: NMAM or OSHA Methods
Personal Protection & Sanitation
(See protection)
Skin: Frostbite
Eyes: Frostbite
Wash skin: No recommendation
Remove: When wet (flammable)
Change: No recommendation
Provide: Frostbite wash
First Aid
(See procedures)
Eye: Frostbite
Skin: Frostbite
Breathing: Respiratory support

Respirator Recommendations
NIOSH
Up to 350 ppm:
(APF = 10) Any supplied-air respirator
Up to 875 ppm:
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode
Up to 1200 ppm:
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concern†
(APF = 50) Any self-contained breathing apparatus with a full facepiece
(APF = 50) Any supplied-air respirator with a full facepiece
Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concern†/Any appropriate escape-type, self-contained breathing apparatus
Important additional information about respirator selection
Exposure Routes
inhalation, skin and/or eye contact (liquid)
Symptoms
Headache, tachypnea, nausea, lassitude (weakness, exhaustion), dizziness, confusion, hallucinations; cyanosis; depressed S-T segment of electrocardiogram, angina, syncope
Target Organs
cardiovascular system, lungs, blood, central nervous system
See also: INTRODUCTION   See ICSC CARD: 0023   See MEDICAL TESTS: 0040