NIOSH Publication No. 2005-151:

NIOSH Pocket Guide to Chemical Hazards

September 2005

1,1,2-Trichloro-1,2,2-trifluoroethane

CAS
76-13-1

CCl2FCClF2

RTECS
KJ4000000
Synonyms & Trade Names

Chlorofluorocarbon-113, CFC-113, Freon® 113, Genetron® 113, Halocarbon 113, Refrigerant 113, TTE
DOT ID & Guide

Exposure
Limits

NIOSH REL: TWA 1000 ppm (7600 mg/m3) ST 1250 ppm (9500 mg/m3)
OSHA PEL: TWA 1000 ppm (7600 mg/m3)
IDLH
2000 ppm See: 76131
Conversion
1 ppm = 7.67 mg/m3
Physical Description
Colorless to water-white liquid with an odor like carbon tetrachloride at high concentrations. [Note: A gas above 118°F.]
MW: 187.4
BP: 118°F
FRZ: -31°F
Sol(77°F): 0.02%
VP: 285 mmHg
IP: 11.99 eV

Sp.Gr(77°F): 1.56
Fl.P: ?
UEL: ?
LEL: ?

Noncombustible Liquid at ordinary temperatures, but the gas will ignite and burn weakly at 1256°F.
Incompatibilities & Reactivities

Chemically-active metals such as calcium, powdered aluminum, zinc, magnesium & beryllium [Note: Decomposes if in contact with alloys containing >2% magnesium.]
Measurement Methods
NIOSH 1020; OSHA 113
See: NMAM or OSHA Methods
Personal Protection & Sanitation
(See protection)
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated
Remove: When wet or contaminated
Change: No recommendation

First Aid
(See procedures)
Eye: Irrigate immediately
Skin: Soap wash promptly
Breathing: Respiratory support
Swallow: Medical attention immediately
Respirator Recommendations
NIOSH/OSHA
Up to 2000 ppm:
(APF = 10) Any supplied-air respirator
(APF = 50) Any self-contained breathing apparatus with a full facepiece
Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure- demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister/Any appropriate escape-type, self-contained breathing apparatus
Important additional information about respirator selection
Exposure Routes
inhalation, ingestion, skin and/or eye contact
Symptoms
Irritation skin, throat, drowsiness, dermatitis; central nervous system depression; in animals: cardiac arrhythmias, narcosis
Target Organs
Skin, heart, central nervous system, cardiovascular system
See also: INTRODUCTION   See ICSC CARD: 0050