NIOSH Publication No. 2005-151:

NIOSH Pocket Guide to Chemical Hazards

September 2005

Antimony

CAS
7440-36-0

Sb

RTECS
CC4025000
Synonyms & Trade Names

Antimony metal, Antimony powder, Stibium
DOT ID & Guide
1549 / 157 (inorganic compounds, n.o.s.)
2871 / 170 (powder)
3141 / 157 (inorganic liquid compounds, n.o.s.)

Exposure
Limits

NIOSH REL*: TWA 0.5 mg/m3 [*Note: The REL also applies to other antimony compounds (as Sb).]
OSHA PEL*: TWA 0.5 mg/m3 [*Note: The PEL also applies to other antimony compounds (as Sb).]
IDLH
50 mg/m3 (as Sb) See: 7440360
Conversion
Physical Description
Silver-white, lustrous, hard, brittle solid; scale-like crystals; or a dark-gray, lustrous powder.
MW: 121.8
BP: 2975°F
MLT: 1166°F
Sol: Insoluble
VP: 0 mmHg (approx)
IP: NA

Sp.Gr: 6.69
Fl.P: NA
UEL: NA
LEL: NA

Noncombustible Solid in bulk form, but a moderate explosion hazard in the form of dust when exposed to flame.
Incompatibilities & Reactivities

Strong oxidizers, acids, halogenated acids [Note: Stibine is formed when antimony is exposed to nascent (freshly formed) hydrogen.]
Measurement Methods
NIOSH 7301, 7303, P&CAM261 (II-4); OSHA ID121, ID125G, ID206
See: NMAM or OSHA Methods
Personal Protection & Sanitation
(See protection)
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated
Remove: When wet or contaminated
Change: Daily

First Aid
(See procedures)
Eye: Irrigate immediately
Skin: Soap wash immediately
Breathing: Respiratory support
Swallow: Medical attention immediately
Respirator Recommendations
NIOSH/OSHA
Up to 5 mg/m3:
(APF = 10) Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100, P100. Click here for information on selection of N, R, or P filters.
(APF = 10) Any supplied-air respirator
Up to 12.5 mg/m3:
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode
(APF = 25) Any powered air-purifying respirator with a high-efficiency particulate filter.
Up to 25 mg/m3:
(APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters.
(APF = 50) Any supplied-air respirator that has a tight-fitting facepiece and is operated in a continuous-flow mode
(APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter
(APF = 50) Any self-contained breathing apparatus with a full facepiece
(APF = 50) Any supplied-air respirator with a full facepiece
Up to 50 mg/m3:
(APF = 1000) Any supplied-air respirator operated in a pressure-demand or other positive-pressure mode
Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters./Any appropriate escape-type, self-contained breathing apparatus
Important additional information about respirator selection
Exposure Routes
inhalation, ingestion, skin and/or eye contact
Symptoms
Irritation eyes, skin, nose, throat, mouth; cough; dizziness; headache; nausea, vomiting, diarrhea; stomach cramps; insomnia; anorexia; unable to smell properly
Target Organs
Eyes, skin, respiratory system, cardiovascular system
See also: INTRODUCTION   See ICSC CARD: 0775   See MEDICAL TESTS: 0016