NIOSH Publication No. 2005-151:

NIOSH Pocket Guide to Chemical Hazards

September 2005

Carbon black

CAS
1333-86-4

C

RTECS
FF5800000
Synonyms & Trade Names

Acetylene black, Channel black, Furnace black, Lamp black, Thermal black
DOT ID & Guide

Exposure
Limits

NIOSH REL: TWA 3.5 mg/m3 Ca TWA 0.1 mg PAHs/m3 [Carbon black in presence of polycyclic aromatic hydrocarbons (PAHs)] See Appendix A See Appendix C
OSHA PEL: TWA 3.5 mg/m3
IDLH
1750 mg/m3 See: 1333864
Conversion
Physical Description
Black, odorless solid.
MW: 12.0
BP: Sublimes
MLT: Sublimes
Sol: Insoluble
VP: 0 mmHg (approx)
IP: NA

Sp.Gr: 1.8-2.1
Fl.P: NA
UEL: NA
LEL: NA

Combustible Solid that may contain flammable hydrocarbons.
Incompatibilities & Reactivities

Strong oxidizers such as chlorates, bromates & nitrates
Measurement Methods
NIOSH 5000; OSHA ID196
See: NMAM or OSHA Methods
Personal Protection & Sanitation
(See protection)
Skin: No recommendation
Eyes: Prevent eye contact
Wash skin: Daily
Remove: No recommendation
Change: No recommendation

First Aid
(See procedures)
Eye: Irrigate promptly

Breathing: Fresh air

Respirator Recommendations
NIOSH/OSHA
Up to 17.5 mg/m3:
(APF = 5) Any quarter-mask respirator. Click here for information on selection of N, R, or P filters.
Up to 35 mg/m3:
(APF = 10) Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100, P100. Click here for information on selection of N, R, or P filters.
(APF = 10) Any supplied-air respirator
Up to 87.5 mg/m3:
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode
(APF = 25) Any powered air-purifying respirator with a high-efficiency particulate filter.
Up to 175 mg/m3:
(APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters.
(APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter
(APF = 50) Any self-contained breathing apparatus with a full facepiece
(APF = 50) Any supplied-air respirator with a full facepiece
Up to 1750 mg/m3:
(APF = 1000) Any supplied-air respirator operated in a pressure-demand or other positive-pressure mode
Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters./Any appropriate escape-type, self-contained breathing apparatus
In presence of polycyclicaromatic hydrocarbons:
NIOSH
At concentrations above the NIOSH REL, or where there is no REL, at any detectable concentration:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters./Any appropriate escape-type, self-contained breathing apparatus
Important additional information about respirator selection
Exposure Routes
inhalation, skin and/or eye contact
Symptoms
Cough; irritation eyes; in presence of polycyclic aromatic hydrocarbons: [potential occupational carcinogen]
Target Organs
respiratory system, eyes

Cancer Site
[lymphatic cancer (in presence of PAHs)]
See also: INTRODUCTION   See ICSC CARD: 0471   See MEDICAL TESTS: 0038