NIOSH Publication No. 2005-151:

NIOSH Pocket Guide to Chemical Hazards

September 2005

Dichlorvos

CAS
62-73-7

(CH3O)2P(O)OCH=CCl2

RTECS
TC0350000
Synonyms & Trade Names

DDVP; 2,2-Dichlorovinyl dimethyl phosphate
DOT ID & Guide
2783 / 152

Exposure
Limits

NIOSH REL: TWA 1 mg/m3 [skin]
OSHA PEL: TWA 1 mg/m3 [skin]
IDLH
100 mg/m3 See: 62737
Conversion
1 ppm = 9.04 mg/m3
Physical Description
Colorless to amber liquid with a mild, chemical odor. [Note: Insecticide that may be absorbed on a dry carrier.]
MW: 221.0
BP: Decomposes
FRZ: ?
Sol: 0.5%
VP: 0.01 mmHg
IP: ?

Sp.Gr(77°F): 1.42
Fl.P: >175°F
UEL: ?
LEL: ?

Class III Combustible Liquid
Incompatibilities & Reactivities

Strong acids, strong alkalis [Note: Corrosive to iron & mild steel.]
Measurement Methods
NIOSH P&CAM295 (II-5); OSHA 62
See: NMAM or OSHA Methods
Personal Protection & Sanitation
(See protection)
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated
Remove: When wet or contaminated
Change: No recommendation

First Aid
(See procedures)
Eye: Irrigate immediately
Skin: Soap wash immediately
Breathing: Respiratory support
Swallow: Medical attention immediately
Respirator Recommendations
NIOSH/OSHA
Up to 10 mg/m3:
(APF = 10) Any supplied-air respirator
Up to 25 mg/m3:
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode
Up to 50 mg/m3:
(APF = 50) Any supplied-air respirator that has a tight-fitting facepiece and is operated in a continuous-flow mode
(APF = 50) Any self-contained breathing apparatus with a full facepiece
(APF = 50) Any supplied-air respirator with a full facepiece
Up to 100 mg/m3:
(APF = 1000) Any supplied-air respirator operated in a pressure-demand or other positive-pressure mode
Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister having an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters./Any appropriate escape-type, self-contained breathing apparatus
Important additional information about respirator selection
Exposure Routes
inhalation, skin absorption, ingestion, skin and/or eye contact
Symptoms
Irritation eyes, skin; miosis, ache eyes; rhinorrhea (discharge of thin mucus); headache; chest tightness, wheezing, laryngeal spasm, salivation; cyanosis; anorexia, nausea, vomiting, diarrhea; sweating; muscle fasciculation, paralysis, dizziness, ataxia; convulsions; low blood pressure, cardiac irregularities
Target Organs
Eyes, skin, respiratory system, cardiovascular system, central nervous system, blood cholinesterase
See also: INTRODUCTION   See ICSC CARD: 0690   See MEDICAL TESTS: 0076