1-Dodecanethiol
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CAS
112-55-0
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CH3(CH2)11SH
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RTECS
JR3155000
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Synonyms & Trade Names
Dodecyl mercaptan, 1-Dodecyl mercaptan, n-Dodecyl mercaptan, Lauryl mercaptan, n-Lauryl mercaptan, 1-Mercaptododecane
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DOT ID & Guide
1228 / 131
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Exposure Limits
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NIOSH REL: C 0.5 ppm (4.1 mg/m3) [15-minute]
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OSHA PEL: none
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IDLH
N.D.
See: IDLH INDEX
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Conversion
1 ppm = 8.28 mg/m3
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Physical Description
Colorless, water-white, or pale-yellow, oily liquid with a mild, skunk-like odor. [Note: A solid below 15°F.]
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MW: 202.4
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BP: 441-478°F
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FRZ: 15°F
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Sol: Insoluble
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VP(77°F): 3 mmHg
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IP: ?
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Sp.Gr: 0.85
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Fl.P(oc): 190°F
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UEL: ?
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LEL: ?
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Class IIIA Combustible Liquid: Fl.P. at or above 140°F and below 200°F.
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Incompatibilities & Reactivities
Strong oxidizers & acids, strong bases, reducing agents, alkali metals, water, steam
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Measurement Methods
None available
See: NMAM or OSHA Methods |
Personal Protection & Sanitation (See protection)
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated
Remove: When wet or contaminated
Change: No recommendation
Provide: Eyewash
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First Aid (See procedures)
Eye: Irrigate immediately
Skin: Soap wash immediately
Breathing: Respiratory support
Swallow: Medical attention immediately
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Respirator Recommendations
NIOSH
Up to 5 ppm: (APF = 10) Any chemical cartridge respirator with organic vapor cartridge(s) (APF = 10) Any supplied-air respirator
Up to 12.5 ppm: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode (APF = 25) Any powered, air-purifying respirator with organic vapor cartridge(s)
Up to 25 ppm: (APF = 50) Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s) (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister (APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and organic vapor cartridge(s) (APF = 50) Any self-contained breathing apparatus with a full facepiece (APF = 50) Any supplied-air respirator with a full facepiece
Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode (APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape: (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister/Any appropriate escape-type, self-contained breathing apparatus
Important additional information about respirator selection
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Exposure Routes
inhalation, ingestion, skin and/or eye contact
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Symptoms
Irritation eyes, skin, respiratory system; cough; dizziness, dyspnea (breathing difficulty), lassitude (weakness, exhaustion), confusion, cyanosis; abdominal pain, nausea; skin sensitization
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Target Organs
Eyes, skin, respiratory system, central nervous system, blood
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See also: INTRODUCTION
See ICSC CARD: 0042 |