NIOSH Publication No. 2005-151:

NIOSH Pocket Guide to Chemical Hazards

September 2005

Selenium

CAS
7782-49-2

Se

RTECS
VS7700000
Synonyms & Trade Names

Elemental selenium, Selenium alloy
DOT ID & Guide
2658 / 152 (powder)

Exposure
Limits

NIOSH REL*: TWA 0.2 mg/m3 [*Note: The REL also applies to other selenium compounds (as Se) except Selenium hexafluoride.]
OSHA PEL*: TWA 0.2 mg/m3 [*Note: The PEL also applies to other selenium compounds (as Se) except Selenium hexafluoride.]
IDLH
1 mg/m3 (as Se) See: 7782492
Conversion
Physical Description
Amorphous or crystalline, red to gray solid. [Note: Occurs as an impurity in most sulfide ores.]
MW: 79.0
BP: 1265°F
MLT: 392°F
Sol: Insoluble
VP: 0 mmHg (approx)
IP: NA

Sp.Gr: 4.28
Fl.P: NA
UEL: NA
LEL: NA

Combustible Solid
Incompatibilities & Reactivities

Acids, strong oxidizers, chromium trioxide, potassium bromate, cadmium
Measurement Methods
NIOSH 7300, 7301, 7303, 9102, S190 (II-7); OSHA ID121
See: NMAM or OSHA Methods
Personal Protection & Sanitation
(See protection)
Skin: Prevent skin contact
Eyes: No recommendation
Wash skin: When contaminated
Remove: When wet or contaminated
Change: No recommendation
Provide: Quick drench
First Aid
(See procedures)
Eye: Irrigate immediately
Skin: Soap wash immediately
Breathing: Respiratory support
Swallow: Medical attention immediately
Respirator Recommendations
NIOSH/OSHA
Up to 1 mg/m3:
(APF = 5) Any quarter-mask respirator. Click here for information on selection of N, R, or P filters.*
(APF = 10) Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100, P100. Click here for information on selection of N, R, or P filters.*
(APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters.
(APF = 25) Any powered air-purifying respirator with a high-efficiency particulate filter.*
(APF = 10) Any supplied-air respirator*
(APF = 50) Any self-contained breathing apparatus with a full facepiece
Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters./Any appropriate escape-type, self-contained breathing apparatus
Important additional information about respirator selection
Exposure Routes
inhalation, ingestion, skin and/or eye contact
Symptoms
Irritation eyes, skin, nose, throat; visual disturbance; headache; chills, fever; dyspnea (breathing difficulty), bronchitis; metallic taste, garlic breath, gastrointestinal disturbance; dermatitis; eye, skin burns; in animals: anemia; liver necrosis, cirrhosis; kidney, spleen damage
Target Organs
Eyes, skin, respiratory system, liver, kidneys, blood, spleen
See also: INTRODUCTION   See ICSC CARD: 0072   See MEDICAL TESTS: 0202