NIOSH Publication No. 2005-151:

NIOSH Pocket Guide to Chemical Hazards

September 2005

Silica, crystalline (as respirable dust)

CAS
14808-60-7

SiO2

RTECS
VV7330000
Synonyms & Trade Names

Cristobalite, Quartz, Tridymite, Tripoli
DOT ID & Guide

Exposure
Limits

NIOSH REL: Ca TWA 0.05 mg/m3 See Appendix A
OSHA PEL:See Appendix C (Mineral Dusts)
IDLH
Ca [25 mg/m3 (cristobalite, tridymite); 50 mg/m3 (quartz, tripoli) See: 14808607
Conversion
Physical Description
Colorless, odorless solid. [Note: A component of many mineral dusts.]
MW: 60.1
BP: 4046°F
MLT: 3110°F
Sol: Insoluble
VP: 0 mmHg (approx)
IP: NA

Sp.Gr: 2.66
Fl.P: NA
UEL: NA
LEL: NA

Noncombustible Solid
Incompatibilities & Reactivities

Powerful oxidizers: fluorine, chlorine trifluoride, manganese trioxide, oxygen difluoride, hydrogen peroxide, etc.; acetylene; ammonia
Measurement Methods
NIOSH 7500, 7601, 7602; OSHA ID142
See: NMAM or OSHA Methods
Personal Protection & Sanitation
(See protection)
Skin: No recommendation
Eyes: No recommendation
Wash skin: No recommendation
Remove: No recommendation
Change: No recommendation

First Aid
(See procedures)
Eye: Irrigate immediately

Breathing: Fresh air

Respirator Recommendations
NIOSH
Up to 0.5 mg/m3:
(APF = 10) Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100, P100. Click here for information on selection of N, R, or P filters.
Up to 1.25 mg/m3:
(APF = 25) Any powered, air-purifying respirator with a high-efficiency particulate filter
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode
Up to 2.5 mg/m3:
(APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters.
(APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter
Up to 25 mg/m3:
(APF = 1000) Any supplied-air respirator operated in a pressure-demand or other positive-pressure mode
Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters./Any appropriate escape-type, self-contained breathing apparatus
Important additional information about respirator selection
Exposure Routes
inhalation, skin and/or eye contact
Symptoms
Cough, dyspnea (breathing difficulty), wheezing; decreased pulmonary function, progressive respiratory symptoms (silicosis); irritation eyes; [potential occupational carcinogen]
Target Organs
Eyes, respiratory system

Cancer Site
[in animals: lung cancer]
See also: INTRODUCTION   See ICSC CARD: 0808